1,2-Arylboration of aliphatic alkenes by cooperative palladium/copper catalysis

TETRAHEDRON LETTERS

卷:72

Article

Semba, Kazuhiko¹  Ohtagaki, Yasuhiro¹  Nakao, Yoshiaki¹ 

[1] Kyoto Univ, Grad Sch Engn, Dept Mat Chem, Nishikyo Ku, Kyoto 6158510, Japan

关键词: Alkenes;    Palladium;    Copper;    Carboboration;    Cooperative catalysis;   

DOI  :  10.1016/j.tetlet.2021.153059

来源: Elsevier

【 摘 要 】

A method for the 1,2-arylboration of aliphatic alkenes to afford alkylboronic esters by cooperative palladium/copper catalysis was developed. The reaction proceeds in a highly regioselective manner, and various functional groups such as silyl ether, alkoxycarbonyl, and cyano groups are tolerated under the applied reaction conditions. (C) 2021 Elsevier Ltd. All rights reserved.

【 授权许可】

Free