Transient materials from thermally-sensitive polycarbonates and polycarbonate nanocomposites

POLYMER

卷:101

Article

Camera, Katherine L.¹  Wenning, Brandon¹  Lal, Amit²  Ober, Christopher K.³ 

[1] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

[2] Cornell Univ, Dept Elect & Comp Engn, Ithaca, NY 14853 USA

[3] Cornell Univ, Dept Mat Sci & Engn, 310 Bard Hall, Ithaca, NY 14853 USA

关键词: Polycarbonates;    Thermal degradation;    Acid catalysis;    Young's modulus;    OMMT;   

DOI  :  10.1016/j.polymer.2016.08.050

来源: Elsevier

【 摘 要 】

Transient materials, or materials with designed short lifetimes, are of great interest in many fields of research. This work describes the development of polycarbonates as a thermally-triggered vaporizable substrate platform. Good mechanical properties over operational temperature ranges in combination with fast and clean decomposition at slightly higher temperatures create an effective transient substrate. Therefore, characterization of the thermal and mechanical properties of vaporizable polycarbonates (VPC) and their composites are indispensable for creating such materials systems. A tailor-made VPC and its blends with a commercially available poly(propylene carbonate) were investigated. Both poly carbonates have acid sensitive backbones; therefore, when combined with an acid source, catalyzed decomposition was observed within minutes, achieving a range of decomposition temperatures between 160 degrees C and 250 degrees C. Polymer with organo-modified montrnorillonite nanocomposites were investigated to provide structural support. These nanocomposites resulted in Young's moduli ranging from 4 MPa to similar to 2 GPa. Their tunable nature allows for designer control over the substrate's properties based on application needs. (C) 2016 Elsevier Ltd. All rights reserved.

【 授权许可】

Free