Proton binding by linear, branched, and hyperbranched polyelectrolytes

POLYMER

卷:51

Article

Koper, Ger J. M.¹  Borkovec, Michal² 

[1] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands

[2] Univ Geneva, Dept Inorgan Analyt & Appl Chem, CH-1205 Geneva, Switzerland

关键词: Proton binding;    Weak polyelectrolytes;    Conformation;   

DOI  :  10.1016/j.polymer.2010.08.067

来源: Elsevier

【 摘 要 】

This article reviews our understanding of ionization processes of weak polyelectrolytes The emphasis is put on a general introduction to site binding models which are able to account for many experimental features of linear and branched polyelectrolytes including dendrimers These models are fully compatible with the classical description of acid-base equilibria The review further discusses the nature of the site-site interaction and role of conformational equilibria Experimental charging data of numerous weak polyelectrolytes are discussed in terms of these models in detail (C) 2010 Elsevier Ltd All rights reserved

【 授权许可】

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