Temperature dependent fracture behavior in model epoxy networks with nanoscale heterogeneity

POLYMER

卷:221

Article

Eaton, Matthew D.¹  Brinson, L. Catherine²  Shull, Kenneth R.¹ 

[1] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA

[2] Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA

关键词: Epoxies;    Fracture toughness;    Network topology;   

DOI  :  10.1016/j.polymer.2021.123560

来源: Elsevier

【 摘 要 】

The role of nanoscale heterogeneity on the mode I fracture toughness, KIc, of model epoxy networks has been investigated. Model systems utilized consist of diglycidyl ether of bisphenol A (DGEBA) as the epoxide with a stoichiometric amine mixture of a rigid cycloaliphatic diamine (PACM) and a more flexible, polypropylene glycol based diamine (Jeffamine) at different molar ratios. The molecular weight of the Jeffamine was adjusted to further tailor the epoxy properties. Fracture toughness was measured using single edge notched bend samples and hardness was measured by Vickers indentation. Both measurements were performed at temperatures as low as - 100 ?C to above ambient temperatures. Results are interpreted in the context of the Dugdale model of material toughness where the fracture toughness is expressed in terms of a cohesive zone stress (related to the hardness), the elastic modulus (measured directly) and the crack tip opening displacement (obtained from images of the fracture surfaces). High toughness is obtained in heterogeneous networks where a decrease in the cohesive zone stress is offset by sufficiently large increases in the crack tip opening displacement.

【 授权许可】

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