N-nitrosodimethylamine (NDMA) formation from the zonation of model compounds

WATER RESEARCH

卷:72

Article

Marti, Erica J.^1,2  Pisarenko, Aleksey N.³  Peller, Julie R.⁴  Dickenson, Eric R. V.¹ 

[1] Southern Nevada Water Author, Appl Res & Dev Ctr, Las Vegas, NV 89193 USA

[2] Univ Nevada, Civil & Environm Engn & Construct, Las Vegas, NV 89154 USA

[3] Trussell Technol, San Diego, CA USA

[4] Indiana Univ Northwest, Dept Chem, Gary, IN USA

关键词: N-Nitrosodimethylamine;    NDMA;    ozone;    Nitrosamine;    Disinfection byproduct;    Potable reuse;   

DOI  :  10.1016/j.watres.2014.08.047

来源: Elsevier

【 摘 要 】

Nitrosamines are a class of toxic disinfection byproducts commonly associated with chloramination, of which several were included on the most recent U.S. EPA Contaminant Candidate List. Nitrosamine formation may be a significant barrier to ozonation in water reuse applications, particularly for direct or indirect potable reuse, since recent studies show direct formation during ozonation of natural water and treated wastewaters. Only a few studies have identified precursors which react with ozone to form N-nitrosodimethylamine (NDMA). In this study, several precursor compound solutions, prepared in ultrapure water and treated wastewater, were subjected to a 10 M excess of ozone. In parallel experiments, the precursor solutions in ultrapure water were exposed to gamma radiation to determine NDMA formation as a byproduct of reactions of precursor compounds with hydroxyl radicals. The results show six new NDMA precursor compounds that have not been previously reported in the literature, including compounds with hydrazone and carbamate moieties. Molar yields in deionized water were 61-78% for 3 precursors, 12 -23% for 5 precursors and <4% for 2 precursors. Bromide concentration was important for three compounds (1,1-dimethylhydrazine, acetone dimethylhydrazone and dimethylsulfamide), but did not enhance NDMA formation for the other precursors. NDMA formation due to chloramination was minimal compared to formation due to ozonation, suggesting distinct groups of precursor compounds for these two oxidants. Hydroxyl radical reactions with the precursors will produce NDMA, but formation is much greater in the presence of molecular ozone. Also, hydroxyl radical scavenging during ozonation leads to increased NDMA formation. Molar conversion yields were higher for several precursors in wastewater as compared to deionized water, which could be due to catalyzed reactions with constituents found in wastewater or hydroxyl radical scavenging. (C) 2014 Elsevier Ltd. All rights reserved.

【 授权许可】

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