Synthesis of dialkoxydiphenylsilanes via the rhodium-catalyzed hydrosilylation of aldehydes

TETRAHEDRON LETTERS

卷:60

Article

Nogues, Christophe¹  Argouarch, Gilles¹ 

[1] Univ Rennes, CNRS, ISCR, UMR 6226, F-35000 Rennes, France

关键词: Hydrosilylation;    Rhodium;    Silanes;    Silyl acetals;   

DOI  :  10.1016/j.tetlet.2019.151101

来源: Elsevier

【 摘 要 】

The commercially available rhodium(I) complex [RhCl(CO)(2)](2) (1) was shown to be an effective catalyst for the reduction of carbonyls with organosilanes under mild conditions. This study focusses on the hydrosilylation of aldehydes with diphenylsilane leading to the isolation of a series of dialkoxydiphenylsilanes with low catalytic loading of complex 1. (C) 2019 Elsevier Ltd. All rights reserved.

【 授权许可】

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