Transition-metal-catalyzed etherification of unactivated C-H bonds

TETRAHEDRON LETTERS

卷:56

Article

Liu, Bin¹  Shi, Bing-Feng^1,2 

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China

关键词: Palladium;    Copper;    Etherification;    Unactivated C-H bonds;    C-O bond formation;   

DOI  :  10.1016/j.tetlet.2014.11.039

来源: Elsevier

【 摘 要 】

The formation of C-O bonds is one of the fundamental transformations in organic chemistry. This digest summarizes recent advances in transition-metal-catalyzed etherification of unactivated C-H bonds. Etherification reactions with different directing groups and catalyst systems via C(sp(2))-H and C(sp(3))-H bonds activation are described. (C) 2014 The Authors. Published by Elsevier Ltd.

【 授权许可】

Free