Recent advances of achiral and chiral diene ligands in transition-metal catalyses

TETRAHEDRON LETTERS

卷:60

Article

Hirano, Masafumi¹  Komine, Nobuyuki¹  Arata, Eri¹  Gridneva, Tatiana¹  Hatori, Atsuya¹  Kaizawa, Naoki¹  Kamakura, Kohei¹  Kuramochi, Ayumi¹  Kurita, Shinnosuke¹  Machida, Shuhei¹  Okada, Harumi¹  Sawasaki, Asami¹  Uchino, Takumi¹ 

[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Dept Appl Chem, 2-24-16 Nakacho, Koganei, Tokyo 1848588, Japan

关键词: Cyclic diene ligands;    Percent buried volume;    Steric bulk of cyclic diene ligands;    Catalytic reactions;   

DOI  :  10.1016/j.tetlet.2019.07.015

来源: Elsevier

【 摘 要 】

A series of achiral and chiral diene and the related ligands in transition-metal complexes is evaluated by percent buried volume (%V-bur) based on their molecular structures by X-ray analysis. Steric bulk of cyclic diene ligands in [Ru(acac)(2)L] and [RhClL](2) are sorted in the order of %V-bur. Recent developments on transition-metal catalyses using these ligands such as (i) conjugate arylations, alkenylation, and alkynylation, (ii) imine-arylations and alkenylations, (iii) kinetic resolutions, (iv) allylation, (v) cyclizations, (vi) defluorinations, (vii) C-H bond activations, and (viii) cross-dimerizations are reviewed. (C) 2019 Elsevier Ltd. All rights reserved.

【 授权许可】

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