Structural and electrical properties of metastable defects in hydrogenated amorphous silicon

Article

关键词: A-SI-H;    SPECTRAL DIFFUSION DECAY;    SOLAR-CELLS;    POSITRON-ANNIHILATION;    CONDUCTIVITY CHANGES;    DANGLING BONDS;    THIN-FILMS;    DEGRADATION;    GENERATION;    STABILITY;   

DOI  :  10.1103/PhysRevB.91.245207

来源: SCIE

【 摘 要 】

The structural and electrical properties of metastable defects in various types of hydrogenated amorphous silicon have been studied using a powerful combination of continuous wave electron-paramagnetic resonance spectroscopy, electron spin echo (ESE) decay measurements, and Doppler broadening positron annihilation spectroscopy. The observed dependence of the paramagnetic defect density on the Doppler S parameter indicates that porous, nanosized void-rich materials exhibit higher spin densities, while dense, divacancy-dominated materials show smaller spin densities. However, after light soaking more similar spin densities are observed, indicating a long-term defect creation process in the Staebler-Wronski effect that does not depend on the a-Si: H nanostructure. From ESE decays it appears that there are fast and slowly relaxing defect types, which are linked to various defect configurations in small and large open volume deficiencies. A nanoscopic model for the creation of light-induced defects in the a-Si: H nanostructure is proposed.

【 授权许可】

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