Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis

Catalysts

Zi-Kui Liu¹  Xiao-Qiang Hu¹  Wen-Jing Xiao² 

[1] Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, School of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, China;Key Laboratory of Pesticide & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University (CCNU), Wuhan 430079, China;

关键词: radical carbonylation;    acyl radical;    visible light photocatalysis;    heterocycles;   

DOI  :  10.3390/catal10091054

来源: DOAJ

【 摘 要 】

Visible light photocatalytic radical carbonylation has been established as a robust tool for the efficient synthesis of carbonyl-containing compounds. Acyl radicals serve as the key intermediates in these useful transformations and can be generated from the addition of alkyl or aryl radicals to carbon monoxide (CO) or various acyl radical precursors such as aldehydes, carboxylic acids, anhydrides, acyl chlorides or α-keto acids. In this review, we aim to summarize the impact of visible light-induced acyl radical carbonylation reactions on the synthesis of oxygen and nitrogen heterocycles. The discussion is mainly categorized based on different types of acyl radical precursors.

【 授权许可】

Unknown