Wetting and Evaporation of Solvents on Thin Soluble Substrates

Colloids and Interfaces

Christian Wolf¹  Tatiana Gambaryan-Roisman¹ 

[1] Institute for Technical Thermodynamics, Technical University of Darmstadt, 64287 Darmstadt, Germany;

关键词: wetting of soluble substrates;    spreading;    evaporation;    polymer coating;    surface topography;   

DOI  :  10.3390/colloids4040048

来源: DOAJ

【 摘 要 】

In this work, the wetting and evaporation behaviour of non-polar solvent droplets on thin soluble coatings is investigated experimentally. The wetting process on spin-coated polymer layers by toluene is captured using shadowgraphy. Initial spontaneous dynamic wetting as well as later stages of wetting are recorded and evaluated. Furthermore, structures obtained by wetting and subsequent evaporation of solvents on polymer coatings are studied by confocal microscopy. The solubility of the substrate has been varied by using polymers with different molecular masses. We observe that initial spreading dynamics does not depend on the molar mass in the studied range. However, we find a strong influence of the molar mass on the late stage wetting dynamics and on the surface structure after solvent evaporation.

【 授权许可】

Unknown