期刊论文详细信息
Materials Research
Chemsensor of NO2 gas based on porphyrin of 5, 10, 15, 20-tetraphenylporphyrin LB films and LS films
关键词: molecular film;    Langmuir-Blodgett film;    chemsensor;    uv-vis spectroscopy;   
DOI  :  10.1590/S1516-14392008000400017
来源: DOAJ
【 摘 要 】

The sensitivity of 5, 10, 15, 20-tetraphenylporphyrin (H2TPP) to the presence of NO2 gas in diluted solutions and in Langmuir-Blodgett (LB) and Langmuir-Schaefer (LS) films was investigated by UV-visible spectroscopy. The shift of Soret and Q bands were analyzed and the energies involved were calculated. The exposure of LB porphyrin films deposited onto glass slides to NO2 has performed as an active chemsensor with 7000 ppm gas concentration. Furthermore, the UV-vis dichroism absorption results associated with the Soret bands have given evidence of the tilt angle of the macrocycle related to the substrate. H2TPP in LB film was tilted by an angle of 51 ± 5° and in the LS film was tilted by an angle of 36° ± 5° indicating the formation of a preferential organization of the molecular films depending on the deposition method.

【 授权许可】

Unknown   

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