Chemsensor of NO2 gas based on porphyrin of 5, 10, 15, 20-tetraphenylporphyrin LB films and LS films

Materials Research

Nelício Faria De Sales¹  Herman Sander Mansur¹ 

[1] ,Federal University of Minas Gerais Laboratory of Material and Surface Characterization Department of Metallurgical and Materials EngineeringBelo Horizonte MG ,Brazil

关键词: molecular film;    Langmuir-Blodgett film;    chemsensor;    uv-vis spectroscopy;   

DOI  :  10.1590/S1516-14392008000400017

来源: SciELO

【 摘 要 】

The sensitivity of 5, 10, 15, 20-tetraphenylporphyrin (H2TPP) to the presence of NO2 gas in diluted solutions and in Langmuir-Blodgett (LB) and Langmuir-Schaefer (LS) films was investigated by UV-visible spectroscopy. The shift of Soret and Q bands were analyzed and the energies involved were calculated. The exposure of LB porphyrin films deposited onto glass slides to NO2 has performed as an active chemsensor with 7000 ppm gas concentration. Furthermore, the UV-vis dichroism absorption results associated with the Soret bands have given evidence of the tilt angle of the macrocycle related to the substrate. H2TPP in LB film was tilted by an angle of 51 ± 5° and in the LS film was tilted by an angle of 36° ± 5° indicating the formation of a preferential organization of the molecular films depending on the deposition method.

【 授权许可】

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