Hydrothermal Synthesis of Cobalt Ruthenium Sulfides as Promising Pseudocapacitor Electrode Materials

Coatings

Ravi Bolagam¹  Sukkee Um¹ 

[1]Department of Mechanical Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Korea

关键词: cobalt ruthenium sulfide;    supercapacitor;    hydrothermal method;    ternary metal sulfides;    electrochemical impedance spectrum;   

DOI  :  10.3390/coatings10030200

来源: DOAJ

【 摘 要 】

In this paper, we report the successful synthesis of cobalt ruthenium sulfides by a facile hydrothermal method. The structural aspects of the as-prepared cobalt ruthenium sulfides were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy. All the prepared materials exhibited nanocrystal morphology. The electrochemical performance of the ternary metal sulfides was investigated by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy techniques. Noticeably, the optimized ternary metal sulfide electrode exhibited good specific capacitances of 95 F g⁻¹ at 5 mV s⁻¹ and 75 F g⁻¹ at 1 A g⁻¹, excellent rate capability (48 F g⁻¹ at 5 A g⁻¹), and superior cycling stability (81% capacitance retention after 1000 cycles). Moreover, this electrode demonstrated energy densities of 10.5 and 6.7 Wh kg⁻¹ at power densities of 600 and 3001.5 W kg⁻¹, respectively. These attractive properties endow proposed electrodes with significant potential for high-performance energy storage devices.

【 授权许可】

Unknown