Effects of Physicochemical Parameters on Struvite Crystallization Based on Kinetics

International Journal of Environmental Research and Public Health

Meng Sun¹  Yuanyuan Shao²  Yifan Li²  Jinzhu Wu²  Baojian Xu²  Jing Wang²  Bing Liu²  Mei Li²  Feiyong Chen² 

[1] Faculty of Environmental Engineering, The University of Kitakyushu, 1-1, Hibikino, Wakamatsu, Kitakyushu 802-8577, Japan;Resources and Environment Innovation Institute, School of Municipal and Environmental Engineering, Shandong Jianzhu University, Jinan 250101, China;

关键词: phosphate recovery;    struvite;    chemical precipitation;    crystallization kinetics;   

DOI  :  10.3390/ijerph19127204

来源: DOAJ

【 摘 要 】

The precipitation of struvite (MgNH₄PO₄·6H₂O) is considered to be a promising method for the recovery of phosphate from wastewater. In this review, the kinetic models, which are commonly used to explain the process of struvite crystallization, are described. The mixed-suspension mixed-product removal (MSMPR) model is based on the population balance equation (the size-dependent growth model and the size-independent growth model). Thereafter, the first-order kinetic fitting model that aligned with concentration changes in the substrate is summarized. Finally, the several physical and chemical factors that affected the efficiency of struvite crystallization are determined. The supersaturation ratio, which is seen as the driving force of struvite crystallization, is the main factor that influences crystallization; however, it cannot be used in practical applications of engineering because it is indirectly associated with the following factors: pH, the molar ratio of Mg:N:P, and the interference of foreign impurities. In this study, we present conclusions that should be used to guide further research studies, and encourage the engineering practice of wastewater treatment with struvite precipitation.

【 授权许可】

Unknown