Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry

Inorganics

HannahF. Drake¹  JoshuaA. Powell¹  Kun-Yu Wang¹  Tian-Hao Yan¹  Hong-Cai Zhou¹  Fan Chen¹  Liang Feng¹ 

[1] Department of Chemistry, Texas A&M University, College Station, TX 77843-3255, USA;

关键词: metal–organic framework;    organometallic;    coordination bonds;    supramolecular chemistry;    catalysis;   

DOI  :  10.3390/inorganics9040027

来源: DOAJ

【 摘 要 】

Metal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for many decades. Through the years, organometallic chemistry has been incorporated into functional MOF construction for diverse applications. Here, we will focus on how organometallic chemistry is applied in MOF design and modifications from linker-centric and metal-cluster-centric perspectives, respectively. Through structural design, MOFs can function as a tailorable platform for traditional organometallic transformations, including reaction of alkenes, cross-coupling reactions, and C–H activations. Besides, an overview will be made on other application categories of organometallic MOFs, such as gas adsorption, magnetism, quantum computing, and therapeutics.

【 授权许可】

Unknown