Crystal structure of catena-poly[[[(2-ethoxypyrazine-κN)copper(I)]-di-μ2-cyanido] [copper(I)-μ2-cyanido]]

Acta Crystallographica Section E: Crystallographic Communications

Kateryna V. Terebilenko¹  Il'ya A. Gural'skiy¹  Sofiia V. Partsevska¹  Valerii Y. Sirenko¹  Sergey O. Malinkin¹ 

[1] Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, Ukraine;

关键词: crystal structure;    ethoxypyrazine;    cyanides;    copper(i);    metal–organic framework;   

DOI  :  10.1107/S205698901901452X

来源: DOAJ

【 摘 要 】

In the asymmetric unit of the title coordination compound, {[Cu(CN)(C4H3OC2H5N2)][Cu(CN)]}n, there are two Cu atoms with different coordination environments. One CuI ion is coordinated in a triangular coordination geometry by the N atom of the 2-ethoxypyrazine molecule and by two bridging cyanide ligands, equally disordered over two sites exchanging C and N atoms, thus forming polymeric chains parallel to the c axis. The other Cu atom is connected to two bridging cyanide groups disordered over two sites with an occupancy of 0.5 for each C and N atom, and forming an almost linear polymeric chain parallel to the b axis. In the crystal, the two types of chain, which are orthogonal to each other, are connected by cuprophilic Cu...Cu interactions [2.7958 (13) Å], forming two-dimensional metal–organic coordination layers parallel to the bc plane. The coordination framework is further stabilized by weak long-range (electrostatic type) C—H...π interactions between cyano groups and 2-ethoxypyrazine rings.

【 授权许可】

Unknown