Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

Molecules

Luminita Silaghi-Dumitrescu¹  Peter Lönnecke²  Evamarie Hey-Hawkins²  Ioana Georgeta Grosu²  Christiane Berghof² 

[1] Department of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, Romania;Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany;

关键词: 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid;    silver(I) complex;    mixedAg-Cd coordination polymer;   

DOI  :  10.3390/molecules20058020

来源: DOAJ

【 摘 要 】

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.

【 授权许可】

Unknown