Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

Molecules

Ioana Georgeta Grosu¹  Christiane Berghof¹  Peter Lönnecke¹  Luminita Silaghi-Dumitrescu²  Evamarie Hey-Hawkins¹ 

[1] Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany; E-Mails:;Department of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, Romania; E-Mail:

关键词: 2;    2'-(1;    2-phenylenedisulfanediyl)diacetic acid;    silver(I) complex;    mixed Ag-Cd coordination polymer;   

DOI  :  10.3390/molecules20058020

来源: mdpi

【 摘 要 】

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (R_S,R_S,R_S,R_S/S_S,S_S,S_S,S_S)-[Ag{1,2-C₆H₄(SCH₂COOH)₂-κ²S,S'}₂]BF₄ (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag₂Cd₂{1,2-(OOCCH₂S)₂C₆H₄}₃(H₂O)₃ 5H₂O]_n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.