Viscosity, Degree of Polymerization, Water Uptake, and Water Solubility Studies on Experimental Dichloro-BisGMA-Based Dental Composites

Applied Sciences

Abdullah Al-Kahtani¹  Taieb Aouak¹  WaseemSharaf Saeed²  Rawaiz Khan²  Ali Alrahlah²  Abdel-Basit Al-Odayni²  Khalid Almutairi³ 

[1] Chemistry Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia;Engineer Abdullah Bugshan Research Chair for Dental and Oral Rehabilitation, College of Dentistry, King Saud University, Riyadh 11545, Saudi Arabia;Maxillofacial Surgery Department, King Saud Medical City, Ministry of Health, Riyadh 12746, Saudi Arabia;

关键词: dichloro-BisGMA;    resin matrix;    dental composite;    degree of conversion;    water uptake;    water solubility;   

DOI  :  10.3390/app11083577

来源: DOAJ

【 摘 要 】

The objective of this work was to investigate the advantages of using dichloro bisphenol A-glycidyl methacrylate (dCl-BisGMA) as a potential matrix for dental resin composites. A series of model composites containing 65 wt% resin (urethane dimethacrylate/triethylene glycol dimethacrylate/BisGMA as 1:3:1) and 35 wt% silanated silica were prepared. Thus, BisGMA was replaced by dCl-BisGMA as 0, 25, 50, and 100 wt% to obtain UTBC0, UTBC25, UTBC50, and UTBC100, respectively. The composites’ rheological properties, degree of double-bond conversion (DC), water sorption (W_SP), and water solubility (W_SL) were examined. The data revealed a statistically significant reduction in the complex viscosity of composites containing dCl-BisGMA, compared with UTBC0. No significant differences between DCs were detected (p < 0.05). A significant enhancement in the reduction of the dCl-BisGMA composite W_SP was also detected, and conversely, W_SL was increased. Although the viscosity, DC, and W_SP characters were enhanced, a W_SL increase is an undesirable development. However, W_SL is supposedly caused by cyclization of small flexible chains, which is more likely to occur in the presence of hydrophobic monomers such as dCl-BisGMA and more prone to leaching than are crosslinked networks. We concluded that dCl-BisGMA is a monomer that could potentially be used as an alternative or in combination with traditional monomers, including BisGMA, in resin-based dental composites, and it deserves further investigation.

【 授权许可】

Unknown