Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate

Acta Crystallographica Section E: Crystallographic Communications

Habib Nasri¹  Selma Dhifaoui¹  Wafa Harhouri¹  Anna Bujacz² 

[1] Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia;X-Ray Analysis Laboratory, Institute of Technical Biochemistry, Lodz University of Technology, Stefanowskiego 4/10, 90-924 Lodz, Poland;

关键词: crystal structure;    hydrogen bonding;    UV–vis spectra;    iron(II)–porphyrin;    benzylamine;   

DOI  :  10.1107/S2056989015024135

来源: DOAJ

【 摘 要 】

In the title compound, [FeII(C44H24Cl4N4)(C6H5CH2NH2)2]·C6H14 or [FeII(TPP-Cl)(BzNH2)2]·n-hexane [where TPP-Cl and BzNH2 are 5,10,15,20-tetrakis(4-chlorophenyl)porphyrinate and benzylamine ligands, respectively], the FeII cation lies on an inversion centre and is octahedrally coordinated by the four pyrrole N atoms of the porphyrin ligand in the equatorial plane and by two amine N atoms of the benzylamine ligand in the axial sites. The crystal structure also contains one inversion-symmetric n-hexane solvent molecule per complex molecule. The average Fe—Npyrrole bond length [1.994 (3) Å] indicates a low-spin complex. The crystal packing is sustained by N—H...Cl and C—H...Cl hydrogen-bonding interactions and by C—H...π intermolecular interactions, leading to a three-dimensional network structure.

【 授权许可】

Unknown