Crystal structure of 4-bromo-N-(2-hydroxyphenyl)benzamide

Acta Crystallographica Section E

Rodolfo Moreno-Fuquen¹  Vanessa Melo¹  Javier Ellena² 

[1] Departamento de Química – Facultad de Ciencias Naturales y Exactas, Universidad del Valle, Apartado 25360, Santiago de Cali, Colombia;Instituto de Física de São Carlos, IFSC, Universidade de São Paulo, USP, São Carlos, SP, Brazil;

关键词: crystal structure;    benzamide;    hydroxyaniline;    hydrogen bonding;   

DOI  :  10.1107/S1600536814024696

来源: DOAJ

【 摘 要 】

In the title compound, C13H10BrNO2, the mean plane of the non-H atoms of the central amide C—N—C(=O)—C fragment (r.m.s. deviation = 0.004 Å) forms a dihedral angle of 73.97 (12)° with the hydroxy-substituted benzene ring and 25.42 (19)° with the bromo-substituted benzene ring. The two aromatic rings are inclined to one another by 80.7 (2)°. In the crystal, molecules are linked by O—H...O and N—H...O hydrogen bonds, forming chains along [010]. The chains are linked by weak C—H...O hydrogen bonds, forming sheets parallel to (100), and enclosing R33(17) and R32(9) ring motifs.

【 授权许可】

Unknown