N-{(Z)-3-Oxo-3-[(E)-(pyridin-2-ylmethyl)diazenyl]-1-(thiophen-2-yl)prop-1-en-2-yl}benzamide

IUCrData

卷:1

B. Narayana¹  K. N. Subbulakshmi¹  B. K. Sarojini²  Sumati Anthal³  Rajni Kant³  Devinder K. Sharma³ 

[1] Department of Chemistry, Mangalore University, Mangalagangothri 574 199, Mangalore, India;

[2] Department of Studies in Chemistry–Industrial Chemistry, Mangalore University, Mangalagangothri 574 199, India;

[3] X-ray Crystallography Laboratory, Post-Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi 180 006, India;

关键词: crystal structure;    diazo;    benzamide;    hydrogen bonding;    C—H...π interactions;   

DOI  :  10.1107/S2414314616012761

来源: DOAJ

【 摘 要 】

In the title compound, C20H16N4O2S, the thiophene ring subtends dihedral angles of 58.6 (3) and 9.8 (3)° with the benzamide and pyridine rings, respectively, whereas these two rings are inclined to one another by 59.3 (3)°. There is an intramolecular C—H...π interaction present involving the pyridine and benzamide rings. In the crystal, molecules are linked by N—H...O hydrogen bonds, forming chains along the [010] direction. The chains are linked by C—H...S hydrogen bonds and C—H...π interactions, forming sheets parallel to the ab plane.

【 授权许可】

Unknown