Synthesis and Characterization of Cerium(IV) Metallocenes

Inorganics

John C. Gordon¹  Andrew D. Sutton¹  Brian L. Scott²  David L. Clark³ 

[1] Chemistry Division—Inorganic, Isotope and Actinide Chemistry (C-IIAC), Los Alamos National Laboratory, Los Alamos, NM 87545, USA;Materials Synthesis and Integrated Devices (MPA-11), Los Alamos National Laboratory, Los Alamos, NM 87545, USA;National Security Education Centre (NSEC), Los Alamos National Laboratory, Los Alamos, NM 87545, USA;

关键词: cerium;    organometallic;    cyclopentadiene;    crystal structure;   

DOI  :  10.3390/inorganics3040589

来源: DOAJ

【 摘 要 】

By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

【 授权许可】

Unknown