Synthesis and Characterization of Cerium(IV) Metallocenes

Inorganics

Andrew D. Sutton³  David L. Clark¹  Brian L. Scott⁴  John C. Gordon³  Stephen Mansell² 

[1] National Security Education Centre (NSEC), Los Alamos National Laboratory, Los Alamos, NM 87545, USA;id="af1-inorganics-03-00589">1Chemistry Division—Inorganic, Isotope and Actinide Chemistry (C-IIAC), Los Alamos National Laboratory, Los Alamos, NM 87545, U;Chemistry Division—Inorganic, Isotope and Actinide Chemistry (C-IIAC), Los Alamos National Laboratory, Los Alamos, NM 87545, USA;Materials Synthesis and Integrated Devices (MPA-11), Los Alamos National Laboratory, Los Alamos, NM 87545, USA; E-Mail:

关键词: cerium;    organometallic;    cyclopentadiene;    crystal structure;   

DOI  :  10.3390/inorganics3040589

来源: mdpi

【 摘 要 】

By applying a salt metathesis approach between Ce(O^tBu₃)₂(NO₃)₂(THF)₂ and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.