期刊论文详细信息
Molbank | |
Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth | |
Carsten Strohmann1  Annika Schmidt1  Michael Knorr2  Abderrahim Khatyr2  Wafa Arar3  | |
[1] Anorganische Chemie, Technische Universität Dortmund, Otto-Hahn Straße 6, 44227 Dortmund, Germany;Institut UTINAM UMR 6213 CNRS, Université Bourgogne Franche-Comté, 16, Route de Gray, 25030 Besançon, France;Selective Organic-Heterocyclic Synthesis-Biological Activity Evaluation (LR17ESO01), Univesité de Tunis-El Manar, Tunis 2092, Tunisia; | |
关键词: bismuth triiodide; thiocarbamate; thione; crystal structure; hirshfeld analysis; | |
DOI : 10.3390/M1381 | |
来源: DOAJ |
【 摘 要 】
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI3 was reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I2Bi(μ2-I)2BiI2}{κ1-MeOC(=S)N(H)Ph}4] 1. Compound 1 was characterized by IR, UV and NMR spectroscopy, the formation of a dinuclear framework is ascertained by a single-crystal X-ray diffraction study performed at 100 K.
【 授权许可】
Unknown