Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth

Molbank

Carsten Strohmann¹  Annika Schmidt¹  Michael Knorr²  Abderrahim Khatyr²  Wafa Arar³ 

[1] Anorganische Chemie, Technische Universität Dortmund, Otto-Hahn Straße 6, 44227 Dortmund, Germany;Institut UTINAM UMR 6213 CNRS, Université Bourgogne Franche-Comté, 16, Route de Gray, 25030 Besançon, France;Selective Organic-Heterocyclic Synthesis-Biological Activity Evaluation (LR17ESO01), Univesité de Tunis-El Manar, Tunis 2092, Tunisia;

关键词: bismuth triiodide;    thiocarbamate;    thione;    crystal structure;    hirshfeld analysis;   

DOI  :  10.3390/M1381

来源: DOAJ

【 摘 要 】

In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI₃ was reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I₂Bi(μ₂-I)₂BiI₂}{κ¹-MeOC(=S)N(H)Ph}₄] 1. Compound 1 was characterized by IR, UV and NMR spectroscopy, the formation of a dinuclear framework is ascertained by a single-crystal X-ray diffraction study performed at 100 K.

【 授权许可】

Unknown