Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide

Molbank

Egor S. Zhilin¹  Leonid L. Fershtat¹  Dmitry B. Meerov² 

[1] N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Avenue, 119991 Moscow, Russia;Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 4 Kosygina Street, 119991 Moscow, Russia;

关键词: nitrogen heterocycles;    oxadiazoles;    energetic materials;    furoxans;    nitration;    thermal stability;   

DOI  :  10.3390/M1301

来源: DOAJ

【 摘 要 】

Furoxan derivatives enriched with explosophoric functionalities are promising compounds in the preparation of novel energetic materials. Herein, a previously unknown potassium (3-methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide (also referred to as potassium 4-dinitromethyl-3-methylfuroxanate) was synthesized via tandem nitration-reduction reactions of an available (furoxanyl)chloroxime. The structure of the synthesized compound was established by elemental analysis, IR, ¹H, ¹³C and ¹⁴N NMR spectroscopy. Thermal stability and mechanical sensitivity of the prepared compound toward impact and friction were experimentally determined.

【 授权许可】

Unknown