Simultaneous Monitoring of Particle-Bound PAHs Inside a Low-Energy School Building and Outdoors over Two Weeks in France

Atmosphere

Stéphane Le Calvé¹  Céline Liaud¹  Sarah Chouvenc¹ 

[1] Centre National de la Recherche Scientifique, L’Institut de Chimie et Procédés pour L’énergie, Université de Strasbourg, L’environnement et la Santé, UMR 7515, F-67000 Strasbourg, France;

关键词: PAHs;    cascade impactor;    particles;    indoor air quality;    low-energy building;    HPLC-fluorescence;   

DOI  :  10.3390/atmos12010108

来源: DOAJ

【 摘 要 】

The emergence of new super-insulated buildings to reduce energy consumption can lead to a degradation of the indoor air quality. While some studies were carried out to assess the air quality in these super-insulated buildings, they were usually focused on the measurement of gas phase pollutants such as carbon dioxide and volatile organic compounds. This work reports the first measurements of Polycyclic Aromatic Hydrocarbons (PAHs) associated with particles as a function of time and particle size in a low-energy building. The airborne particles were collected indoors and outdoors over three to four days of sampling using two three-stage cascade impactors allowing to sample simultaneously particles with aerodynamic diameter Dae > 10 µm, 2.5 µm < Dae < 10 µm, 1 µm < Dae < 2.5 µm, and Dae < 1 µm. The 16 US-EPA priority PAHs were then extracted and quantified by high-performance liquid chromatography (HPLC) coupled to fluorescence detection. The resulting total particle concentrations were low, in the ranges 3.73 to 9.66 and 0.60 to 8.83 µg m-3 for indoors and outdoors, respectively. Thirteen PAHs were always detected in all the samples. The total PAH concentrations varied between 290 and 415 pg m⁻³ depending on the particle size, the environment (indoors or outdoors) and the sampling period considered. More interestingly, the temporal variations of individual PAHs highlighted that high molecular weight PAHs were mainly associated to the finest particles and some of them exhibited similar temporal behaviors, suggesting a common emission source. The indoor-to-outdoor concentration ratios of individual PAH were usually found close to or less than 1, except during the event combining rainy conditions and limited indoor ventilation rate.

【 授权许可】

Unknown