Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide

Open Chemistry

Puschmann Horst¹  Ajibade Peter A.²  Oyedeji Opeoluwa O.³  Mbese Johannes Z.³  Odularu Ayodele T.³ 

[1] Chemistry Department, Durham University, Dublin, United Kingdom;Department of Chemistry, School of Chemistry and Physics, University of KwaZulu-Natal, Pietermaritzburg Campus, Scottsville 3209, South Africa;Department of Chemistry, University of Fort Hare, Private Bag X1314, Alice 5700, South Africa;

关键词: thiourea;    dimethylformamide;    crystal structure;    monoclinic;   

DOI  :  10.1515/chem-2020-0061

来源: DOAJ

【 摘 要 】

This study is about the synthesis of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide (C16H17Cl2N3OS) compound. Single crystals of the compound were obtained by slow evaporation of N,N′-bis(4-chlorophenyl)thiourea (C13H10Cl2N2S) in N,N-dimethylformamide (C3H7NO; DMF) through recrystallization under mild condition. Important classical N–H⋯O links the two molecules together. Results revealed that C16H17Cl2N3OS crystallized in the monoclinic space group P21/c with the respective cell parameters of a = 92,360 (4) Å, b = 7.2232 (3) Å, 25.2555 (11) Å, β = 91.376 (3), α = γ = 90°, V = 1684.40 (12) Å3, T = 119.94 (13) K and Z = 4 and Z′ = 1.

【 授权许可】

Unknown