CERIUM(III) CARBONATE HYDROXIDE NANOPARTICLES ENCRUSTED BY METALLIC PALLADIUM. SYNTHESIS AND INVESTIGATION

Тонкие химические технологии

V. I. Popenko¹  V. V. Fomichev²  T. M. Buslaeva³  A. M. Potapova³  E. V. Kopylova⁴ 

[1] Engelhardt Institute of Molecular Biology of Russian Academy of Sciences;Moscow Technological University (Institute of Fine Chemical Technologies), Moscow Technological University, Shared Equipment Center;Moscow Technological University (Institute of Fine Chemical Technologies);Moscow Technological University, Shared Equipment Center;

关键词: cerium (iii) carbonate hydroxide;    palladium;    nanoparticles;    synthesis;    hydrogen bonds;    catalysis;   

DOI  :  10.32362/2410-6593-2016-11-1-23-28

来源: DOAJ

【 摘 要 】

Cerium(III) nitrate and urea solution mixture were treated by hydrothermal and microwavehydrothermal methods, as a result cerium(III) carbonate hydroxide nanoparticles (22-37 nm) were obtained. Cerium(III) carbonate hydroxide nanoparticles, encrusted by palladium were obtained using palladium reduction process from cerium(III) carbonate hydroxide solution. It is shown, that palladium occurrence disturbs hard hydrogen bond system, leading to carbonate hydroxide nanoparticles structure disorder and also increases efficiency of catalytic reactivity process.

【 授权许可】

Unknown