Crystal structure of poly[[μ3-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)]

Acta Crystallographica Section E: Crystallographic Communications

Alexander J. Charlson¹  Mohan Madhav Bhadbhade² 

[1] Department of Chemistry and Biomolecular Sciences, Macquarie University, North Ryde, NSW 2109, Australia;Mark Wainwright Analytical Centre, University of New South Wales, Sydney, NSW 2052, Australia;

关键词: palladium–amino acid complex;    L-serine;    single-crystal X-ray structure;    palladium complex;   

DOI  :  10.1107/S2056989017016164

来源: DOAJ

【 摘 要 】

The structure of the title compound, [CsPd(C3H6NO3)Cl2]n, previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated l-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs2SO4 structure. X-ray crystal structures of only three dichloridopalladium(II)–amino acid complexes have been determined so far and the present paper describes one of those.

【 授权许可】

Unknown