Polyaniline-decorated carbon fibers for enhanced mechanical and electromagnetic interference shielding performances of epoxy composites

Materials & Design

Dingxiang Yan¹  Lichuan Jia²  Shuangqin Yi³  Wenjin Sun³  Weiwei Kong⁴  Ling Xu⁴  Zhongming Li⁴ 

[1] Corresponding authors.;College of Electrical Engineering, Sichuan University, Chengdu 610065, People's Republic of China;College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, People's Republic of China;School of Aeronautics and Astronautics, Sichuan University, Chengdu 610065, People's Republic of China;

关键词: Carbon fiber;    Epoxy;    Polyaniline;    Interfacial adhesion;    Electromagnetic interference shielding;   

DOI  :  

来源: DOAJ

【 摘 要 】

The development of carbon fiber-reinforced polymers (CFRPs) with high electromagnetic interference (EMI) shielding effectiveness is highly desirable for engineering applications. Nevertheless, poor interfacial adhesion between carbon fibers (CFs) and polymer matrix remains a serious issue. Herein, a mechanically enhanced CF/epoxy composite with highly efficient EMI shielding was fabricated through in-situ polymerization of polyaniline (PANI) nanolayer. The PANI nanolayer improved the interfacial adhesion in the composites via the entanglement of molecular chains, π–π stacking, and chemical bonding et al. The resulting CF/PANI/epoxy composite exhibited an interlaminar shear strength of 72.8 MPa, which was a 24% improvement over 58.5 MPa for the virgin CF/epoxy composite. Moreover, an excellent EMI shielding effectiveness of 54.8 dB was achieved, which was 58% higher than that of the virgin CF/epoxy composite. This could be attributed to the significant enhancement in conduction loss, interfacial polarization loss, and multiple reflections with the help of PANI nanolayer. This study provides a novel strategy for the development of high-performance CFRPs for efficient EMI shielding.

【 授权许可】

Unknown