期刊论文详细信息
Molecules | |
Transition-Metal-Free C(sp3)–H Oxidation of Diarylmethanes | |
Bihui Zhou1  Limei Fan1  Linlin Li1  Pu Chen1  Wenzhe Ren1  Dong Zou1  Qiannan Luo1  Jie Li1  Fan Yang1  | |
[1] Department of Pharmacy, School of Medicine, Zhejiang University City College, No. 48, Huzhou Road, Hangzhou 310015, China; | |
关键词: metal-free; diarylmethane; oxidation; ketone; | |
DOI : 10.3390/molecules23081922 | |
来源: DOAJ |
【 摘 要 】
An efficient direct C(sp3)–H oxidation of diarylmethanes has been demonstrated by this study. This method employs environment-friendly O2 as an oxidant and is promoted by commercially available MN(SiMe3)2 [M = K, Na or Li], which provides a facile method for the synthesis of various diaryl ketones in excellent yields. This protocol is metal-free, mild and compatible with a number of functional groups on substrates.
【 授权许可】
Unknown