Analysis of Photocatalytic Degradation of Phenol with Exfoliated Graphitic Carbon Nitride and Light-Emitting Diodes Using Response Surface Methodology

Catalysts

Adeem Ghaffar Rana¹  Mirjana Minceva¹ 

[1] Biothermodynamics, TUM School of Life Sciences, Technical University of Munich, Maximus-von-Imhof-Forum 2, 85354 Freising, Germany;

关键词: g-C₃N₄;    photocatalysis;    response surface methodology;    wastewater treatment;    phenol;   

DOI  :  10.3390/catal11080898

来源: DOAJ

【 摘 要 】

Response surface methodology (RSM) involving a Box–Benkhen design (BBD) was employed to analyze the photocatalytic degradation of phenol using exfoliated graphitic carbon nitride (g-C₃N₄) and light-emitting diodes (wavelength = 430 nm). The interaction between three parameters, namely, catalyst concentration (0.25–0.75 g/L), pollutant concentration (20–100 ppm), and pH of the solution (3–10), was examined and modeled. An empirical regression quadratic model was developed to relate the phenol degradation efficiency with these three parameters. Analysis of variance (ANOVA) was then applied to examine the significance of the model; this showed that the model is significant with an insignificant lack of fit and an R² of 0.96. The statistical analysis demonstrated that, in the studied range, phenol concentration considerably affected phenol degradation. The RSM model shows a significant correlation between predicted and experimental values of photocatalytic degradation of phenol. The model’s accuracy was tested for 50 ppm of phenol under optimal conditions involving a catalyst concentration of 0.4 g/L catalysts and a solution pH of 6.5. The model predicted a degradation efficiency of 88.62%, whereas the experimentally achieved efficiency was 83.75%.

【 授权许可】

Unknown