(2Sp,4R,8Sp)-4-Methyl-1-phenyl-diferroceno-5-Z-ethylene-1-phosphinoxide

Molbank

Michael Widhalm¹  Philipp Honegger² 

[1] Institute of Chemical Catalysis, University of Vienna, Währingerstraße 38, 1090 Vienna, Austria;Institute of Computational Biological Chemistry, University of Vienna, Währingerstraße 17, 1090 Vienna, Austria;

关键词: ferrocene;    8-membered cycle;    planar chirality;    hydrovinylation;    titanium(iv) chloride;   

DOI  :  10.3390/M1105

来源: DOAJ

【 摘 要 】

We present a synthesis of the title compound, a homochiral diferroceno cycle intended for use in asymmetric catalysis. We present a hydrovinylation protocol, which allows the production of the title compound in two steps from a known diferrocenyl precursor. We obtained one of two possible diastereomers selectively and propose a plausible regio- and stereoselective reaction mechanism.

【 授权许可】

Unknown