Polymeric Electrochemical Sensor for Calcium Based on DNA

Polymers

Soha F. Mohamed¹  Mohsen M. Zareh¹  Anas M. Elsheikh¹ 

[1] Department of Chemistry, Faculty of Science, Zagazig University, Zagazig 44519, Egypt;

关键词: calcium sensor;    deoxyribonucleic acid ionophore;    calcium determination;   

DOI  :  10.3390/polym14091896

来源: DOAJ

【 摘 要 】

Plastic membranes containing deoxyribonucleic acid (DNA) as an electroactive material were acting as Ca²⁺ selective sensors. Diethyl phthalate (DEP), dioctyl Phthalate (DOP), or nitrophenyl octyl ether (NPOE) were used as plasticizers and polyvinyl chloride (PVC) was the membrane matrix. A sensor with a membrane composition of 120 mg PVC, 60 mg DOP plasticizer, and 2 mg DNA ionophore (DNA: DOP: PVC, 1.0:29.2:0.1 mole) was found to have the best performance. The slope of the calibration graph was 30 mV decade⁻¹. The optimum pH range was 5.7–9.5 for 0.01 M Ca²⁺. The sensor response time was fast (2–3 s) with a long working period (up to 3 weeks). Excellent selectivity for Ca²⁺ was indicated by the values of selectivity coefficients for different selected interference. The sensor was used effectively for the estimation of calcium in real samples (fruits, calcium syrup, milk, and dairy products).

【 授权许可】

Unknown