Recent Advances in the Application of Magnetic Nanoparticles as a Support for Homogeneous Catalysts

Nanomaterials

Yurii K. Gun'ko¹  Joseph Govan¹ 

[1] School of Chemistry and CRANN, Trinity College Dublin, Dublin 2, Ireland;

关键词: magnetic nanoparticles;    catalysis;    magnetic recovery;    homogeneous catalysts;   

DOI  :  10.3390/nano4020222

来源: DOAJ

【 摘 要 】

Magnetic nanoparticles are a highly valuable substrate for the attachment of homogeneous inorganic and organic containing catalysts. This review deals with the very recent main advances in the development of various nanocatalytic systems by the immobilisation of homogeneous catalysts onto magnetic nanoparticles. We discuss magnetic core shell nanostructures (e.g., silica or polymer coated magnetic nanoparticles) as substrates for catalyst immobilisation. Then we consider magnetic nanoparticles bound to inorganic catalytic mesoporous structures as well as metal organic frameworks. Binding of catalytically active small organic molecules and polymers are also reviewed. After that we briefly deliberate on the binding of enzymes to magnetic nanocomposites and the corresponding enzymatic catalysis. Finally, we draw conclusions and present a futureoutlook for the further development of new catalytic systems which are immobilisedonto magnetic nanoparticles.

【 授权许可】

Unknown