Efficient Removal of Cu(II), Zn(II), and Cd(II) from Aqueous Solutions by a Mineral-Rich Biochar Derived from a Spent Mushroom (Agaricus bisporus) Substrate

Materials

Kokyo Oh¹  Guosheng Zhang²  Long Su²  Haibo Zhang²  Na Liu²  Yuan Luo²  Hongyan Cheng² 

[1] Center for Environmental Science in Saitama, Kazo City, Saitama 347-0115, Japan;College of Resources and Environment, Shanxi Agricultural University, Taigu 030801, China;

关键词: spent mushroom substrate;    biochar;    pyrolysis temperature;    mineral;    heavy metal;    sorption characteristic;   

DOI  :  10.3390/ma14010035

来源: DOAJ

【 摘 要 】

This study evaluated the novel application of a mineral-rich biochar derived from a spent Agaricus bisporus substrate (SAS). Biochars with various pyrolysis temperatures (350–750 °C) were used to remove Cu(II), Zn(II), and Cd(II) from aqueous solutions. The adsorption characteristics and removal mechanisms of the biochars were investigated. The adsorption kinetics and isotherm data were fitted well by pseudo-second-order and Freundlich models. The Langmuir maximum removal capacity (Q_max) values of Cu(II), Zn(II), and Cd(II) were ordered as SAS750 > SAS350 > SAS550, and the Q_max values of SAS750 were 68.1, 55.2, and 64.8 mg·g⁻¹, respectively. Overall, the removal mechanisms of biochar at a low production temperature (350 °C) to Cu(II), Zn(II), and Cd(II) were mainly via ion exchange (54.0, 56.0, and 43.0%), and at a moderate production temperature (550 °C), removal mechanisms were mainly via coordination with π electrons (38.3, 45.9, and 55.0%), while mineral precipitation (65.2, 44.4, and 76.3%, respectively) was the dominant mechanism at a high produced temperature (750 °C). The variation of the mutual effect of minerals and heavy metals was the predominant factor in the sorption mechanism of mineral precipitation and ion exchange. The results demonstrated that spent Agaricus bisporus substrate biochar is a potential candidate for the efficient removal of heavy metals, which provides a utilization route for spent mushroom substrates.

【 授权许可】

Unknown