A DFT Investigation on the Origins of Solvent-Dependent Polysulfide Reduction Mechanism in Rechargeable Li-S Batteries

Catalysts

Chi-You Liu¹  Guan-Ying Du¹  EliseY. Li¹ 

[1] Department of Chemistry, National Taiwan Normal University No. 88, Section 4, Tingchow Road, Taipei 116, Taiwan;

关键词: Li-S battery;    donor number;    dielectric constant;    polysulfides;    solvent effect;    DFT;   

DOI  :  10.3390/catal10080911

来源: DOAJ

【 摘 要 】

The lithium-sulfur (Li-S) battery is one of the promising energy storage alternatives because of its high theoretical capacity and energy density. Factors governing the stability of polysulfide intermediates in Li-S batteries are complex and are strongly affected by the solvent used. Herein, the polysulfide reduction and the bond cleavage reactions are calculated in different solvent environments by the density functional theory (DFT) methods. We investigate the relationship between the donor numbers (DN) as well as the dielectric constants (ε) of the solvent system and the relative stability of different polysulfide intermediates. Our results show that the polysulfide reduction mechanism is dominated by its tendency to form the ion-pair with Li⁺ in different organic solvents.

【 授权许可】

Unknown