A Well-Defined {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes

Molecules

Mengping Guo¹  Lanjiang Zhou¹  Jiamin Li¹  Yanping Kang¹  Leiqing Fu¹ 

[1] Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun 336000, China;

关键词: palladium (II) complex;    Hiyama cross-coupling reaction;    unsymmetrical biaryls;    synthetic method;   

DOI  :  10.3390/molecules21080987

来源: DOAJ

【 摘 要 】

A palladium (II) complex {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating.

【 授权许可】

Unknown