CATALYTIC CONVERSION OF FORMIC ACID TO METHANOL WITH Cu AND Al UNDER HYDROTHERMAL CONDITIONS

BioResources

关键词: Biomass utilization;    Catalytic reduction;    Methanol;    Hydrothermal conditions;   

DOI  :  

来源: DOAJ

【 摘 要 】

Catalytic conversion of formic acid into methanol was investigated with Cu as a catalyst and Al as a reductant under hydrothermal conditions. It was found that formic acid can be converted into methanol by such means. The highest yield of methanol (30.4%) was attained with a temperature of 300 °C and a reaction time of 9 h. The AlO(OH) formed from Al oxidation may also play a catalytic role in the formation of methanol. This process may provide a promising solution to producing methanol from carbohydrate biomass combined with the process of converting the carbohydrate into formic acid, which is expected to emit no CO2.

【 授权许可】

Unknown