期刊论文详细信息
Molecules | |
Tandem Catalysis of an Aldol-‘Click’ Reaction System within a Molecular Hydrogel | |
Santiago Díaz-Oltra1  Beatriu Escuder1  Marco Araújo1  Iván Muñoz Capdevila1  | |
[1] Departament de Química Inorgànica i Orgànica, Universitat Jaume I, 12071 Castelló, Spain; | |
关键词: aldol addition; click reaction; tandem catalysis; supramolecular gels; multicomponent system; | |
DOI : 10.3390/molecules21060744 | |
来源: DOAJ |
【 摘 要 】
A heterogeneous supramolecular catalytic system for multicomponent aldol-‘click’ reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent reaction between phenylacetylene, p-nitrobenzaldehyde, and an azide containing a ketone moiety, obtaining the corresponding aldol products in good yields. A possible mechanistic pathway responsible for this unexpected catalytic behavior has been proposed.
【 授权许可】
Unknown