Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes

Green Synthesis and Catalysis

Jun Xuan¹  Qian Li¹  Bao Gui Cai²  Lei Li² 

[1] Chemical Engineering, Anhui University, Hefei 230601, China;;Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry &

关键词: Visible light;    Acylsilanes;    Siloxy carbene;    Oximes;    C–O bond formation;   

DOI  :  

来源: DOAJ

【 摘 要 】

Visible light promoted C–O bond formation reaction through O–H insertion of acylsilanes with oximes has been developed. The reaction occurred under mild reaction conditions (sole blue LED irradiation in the absence of any catalysts or additives) with a short reaction time and afforded the corresponding oxime ethers in moderate to good yields.

【 授权许可】

Unknown