Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical

Beilstein Journal of Organic Chemistry

Hui Wang¹  Santhivardhana Reddy Yetra¹  Zhigao Shen¹  Lutz Ackermann¹ 

[1] Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077 Göttingen, Germany;

关键词: amidation;    C–H activation;    cobalt;    ferrocene;    mechanochemistry;   

DOI  :  10.3762/bjoc.14.131

来源: DOAJ

【 摘 要 】

Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic studies provided strong support for a facile organometallic C–H activation manifold.

【 授权许可】

Unknown