期刊论文详细信息
Catalysts
A Novel Synthetic Route to Prepare High Surface Area Mayenite Catalyst for TCE Oxidation
Antonio Proto1  Raffaele Cucciniello1  Federico Rossi1  Adriano Intiso1  Joaquin Martinez-Triguero2  AntonioEduardo Palomares2 
[1] Department of Chemistry and Biology, University of Salerno, via Giovanni Paolo II 132, 84084 Fisciano (SA), Italy;Instituto de Tecnología Química, Universitat Politècnica de València-CSIC, 46022 Valencia, Spain;
关键词: Mayenite;    TCE;    PMMA;    catalytic oxidation;   
DOI  :  10.3390/catal9010027
来源: DOAJ
【 摘 要 】

Mayenite (Ca12Al14O33) was synthesized by a novel route based on the use of polymethyl methacrylate (PMMA) as a soft templating agent. The material was tested for the total oxidation of trichloroethylene in the gas phase and the catalytic performance was analysed when using different initial amounts of PMMA in the catalyst synthesis. The results were compared with those obtained with a mayenite synthetized by a classical hydrothermal method. The highest activity in terms of TCE conversion was achieved in the presence of mayenite prepared using 10% w/w of PMMA; its activity was also higher than that of the hydrothermal mayenite. The surface area and the number of superoxide anions (O2−) seem to be the main properties determining the catalytic activity of the material.

【 授权许可】

Unknown   

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