Reactivity Ratios for Organotin Copolymer Systems

Molecules

关键词: organotin monomers;    bis(tri-n-butyltin) oxide;    maleate;    itaconate;    styrene;    methyl methacrylate;    reactivity ratio;   

DOI  :  10.3390/molecules15042749

来源: DOAJ

【 摘 要 】

Di(tri-n-butyltin) itaconate (DTBTI) and monoethyl tributyltin fumarate (METBTF) were synthesized as organotin monomers. The organotin monomers were copolymerized with styrene (ST) and methyl methacrylate (MMA) via a free radical polymerization technique. The overall conversion was kept low (£15% wt/wt) for all studied samples and the copolymer composition was determined from tin analysis. The synthesized monomers and copolymers were characterized by elemental analysis, 1H- and 13C-NMR, and FTIR spectroscopy.

【 授权许可】

Unknown