(η4-Bicyclo[2.2.1]hepta-2,5-diene)bis(η2-3,5-di-tert-butyl-1,2,4-diazaphospholido)ruthenium

IUCrData

Wenjun Zheng¹  Lili Ren¹ 

[1] Institute of Organic Chemistry and College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province 041004, People's Republic of China;

关键词: crystal structure;    ruthenium;    1,2,4-diazaphospholide;   

DOI  :  10.1107/S2414314616001103

来源: DOAJ

【 摘 要 】

In the title compound, [Ru(C10H18N2P)2(C7H8)], the two 1,2,4-diazaphospholide (dp) ligands are coordinated to the RuII ion in an almost perfect η2-geometry, with Ru—N bond lengths in the range 2.071 (3)–2.135 (3) Å. The N—Ru—N angles within each η2-1,2,4-diazaphospholide ligand are similar, with values of 37.10 (11) and 37.44 (11)°, and hence the coodination geometry around the RuII ion is highly distorted from the expected octahedral geometry. One of the tert-butyl groups was refined as disordered over two sets of sites, with a ratio of occupancies of 0.719 (6):0.281 (6).

【 授权许可】

Unknown