Crystal structure of [1,2-bis(diphenylphosphanyl)benzene]heptacarbonyldi-μ-hydrido-(μ3-2,4,6-trimethylphenylphosphinidene)-triangulo-triruthenium

Acta Crystallographica Section E: Crystallographic Communications

Taeko Kakizawa¹ 

[1] Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555, Japan;

关键词: crystal structure;    cluster;    phosphine;    ruthenium;   

DOI  :  10.1107/S2056989017007770

来源: DOAJ

【 摘 要 】

The title trinuclear ruthenium cluster, [Ru3(C30H24P2)(C9H11P)(CO)7(μ-H)2], has a triangular Ru3 core that is capped with a mesitylphosphinidene ligand, μ3-PMes (Mes = mesityl = 2,4,6-trimethylphenyl). The 1,2-bis(diphenylphosphanyl)benzene molecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent molecules in the asymmetric unit.

【 授权许可】

Unknown