Crystal structure of bis{μ-1-[(E)-(3-methoxyphenyl)diazenyl]naphthalen-2-olato-κ3N2,O:O}bis({1-[(E)-(3-methoxyphenyl)diazenyl]naphthalen-2-olato-κ2N2,O}copper(II))

Acta Crystallographica Section E: Crystallographic Communications

Christian G. Bochet¹  Jean-Pierre Djukic²  Noudjoud Hamdouni³  Corinne Bailly⁴  Souheyla Chetioui⁵ 

[1] Chemistry Department, University of Fribourg, Chemin du Musee 9, CH-1700 Fribourg, Switzerland;Laboratoire de Chimie et Systémique Organométallique (LCSOM), Institut de Chimie, Université de Strasbourg, UMR 7177, F-67070 Strasbourg Cedex, France;Laboratoire de Cristallographie, Département de Physique, Université Constantine 1, Constantine 25000, Algeria;Service de Radiocristallographie, Institut de Chimie, Université de Strasbourg, UMR 7177, 67008 Strasbourg Cedex, France;Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1, Constantine 25000, Algeria;

关键词: crystal structure;    dinuclear Cu complex;    azo dyes;    hydrogen bonding;   

DOI  :  10.1107/S2056989015020824

来源: DOAJ

【 摘 要 】

The title dinuclear CuII complex, [Cu2(C17H13N2O2)4], is located on an inversion centre. The CuII atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the dinuclear complex, the Cu...Cu separation is 3.366 (3) Å. In the crystal, complex molecules are linked via weak C—H...O hydrogen bonds, forming a layer parallel to (-101).

【 授权许可】

Unknown