New strategy for chemically attachment of Schiff base complexes on Multiwalled Carbon Nanotubes surfaces

Current Chemistry Letters

卷:3

关键词: Multiwalled Carbon;    Nanotubes Microwave irradiation;    Functionalization of MWCNT;    Schiff base;    Salen complex@MWCNTs;   

DOI  :  10.5267/j.ccl.2014.5.004

来源: DOAJ

【 摘 要 】

Chemically attachment of Schiff base complexes on multiwalled carbon nanotubes (MWCNTs) surfaces through a convenient and simple method was studied. In the first step of this method, we present a new method for preparation of aminated MWCNTs in order to attachment of (new) chlorinated salen Schiff bases. Amination of multiwalled carbon nanotubes performed under microwave (MW) irradiation through a one pot two step reaction. The chemically attachment of salen Schiff bases on functionalized MWCNTs (salen@MWCNTs) performed under a facile simple nucleophilic substitution reaction and complexation of attached salen Schiff bases (salen complex@MWCNTs) in last step, have been occurred with reaction of transition metal salts and salen@MWCNTs. The obtained products were characterized in detail, using FTIR, XRD, UV-Vis absorption, SEM and EDX methods.

【 授权许可】

Unknown